Insights on metal pollution of a Patagonia watershed: A case study in the lower course of the Negro river, Argentina.

This study evaluated the occurrence and distribution of largely known pollutants (Ag, Cd, Cu, Cr, Hg, Ni, Pb, Pd, and Zn), as well as emerging ones (Li, and V) in the water dissolved fraction, suspended particulate matter, and surface sediments from the lower course of the Negro River, Argentina. There are scarce preceding data on inorganic pollution in the entire watershed and, in the case of the emerging pollutants, there are almost no studies performed worldwide. Sampling was conducted in 2019 at six sampling sites, three of them mostly river dominated and the rest under marine domain. The samples were subjected to an acid digestion in a microwave digester, and analyzed using an Inductively Coupled Plasma Atomic Emission Spectrometer. Results: revealed that Cu, Li, V, and Zn were always on the top four of the highest average metal concentrations in water and sediment fractions. The pollution assessment indicated that the watershed might be exposed to anthropogenic pollution, as over 60% of Cu and Zn, and over 85% of Hg in water dissolved samples from the marine dominated sites were above the maximum recommended values from guidelines. The multivariate analyses characterized the watershed into two clusters, with metals in the sediment fraction mainly contributing to the uppermost sites. Indeed, sedimentary Cu and Zn background enrichment indices pointed out a moderate pollution of the river dominated sites. This study highlights the relevance of an integrative approach in metal pollution evaluation, as the results denoted a progressive deterioration of the watershed, affecting the water quality of the lower course of the Negro River and its adjacent coastal zone. Overall, these results contribute to a more complete evaluation of the potential to fulfill the Sustainable Development Goals, with implications for future treatment strategies to enhance the environmental quality of the area.

Water quality analysis based on phytoplankton and metal indices: a case study in the Sauce Grande River Basin (Argentina).

The increasing landscape alterations due to anthropogenic activities is of global concern since it affects aquatic ecosystems, often resulting in compromise of the ecological integrity and the water quality. In this sense, the evaluation, monitoring, and prediction of the aquatic ecosystem quality becomes an important research subject. This study presents the first integrated water quality assessment of the Sauce Grande River Basin, in Argentina, based on the spatial distribution of the phytoplankton community, the physicochemical parameters, and the metal concentrations (Cd, Cu, Cr, Fe, Mn, Ni, Pb, and Zn) found in the particulate fraction. According to the trophic indices and the phytoplankton abundance, composition, and diversity, the water quality showed significant deterioration in the lower basin after the Sauce Grande lake. The trophic state index indicated that water was oligotrophic in over 75% of the sampling sites, increasing downstream, where two sites were characterized as mesotrophic, and one described as hypertrophic. The phytoplankton community was dominated by diatoms in zones with low anthropogenic impact and conductivity, whereas high densities of Euglenophyta, Chlorophyta, and Cyanobacteria were found in the middle-lower basin, associated with higher organic matter and eutrophication. The conductivity, turbidity, and most metal concentrations also increased towards the downstream area, even exceeding recommended levels for the metals Cu, Cr, Mn, and Pb in the middle and lower reaches of the basin (Cu: 3.5 µg L-1; Cr: 2.4 µg L-1; Pb: 1.2 µg L-1; Mn 170 µg L-1). This study generates a database for the water quality of the Sauce Grande River Basin and sets an example of how the water quality varies along a basin that crosses different topographic environments, land covers, and anthropogenic influences.

Synthetic microfibers and tyre wear particles pollution in aquatic systems: Relevance and mitigation strategies.

Evidence shows that the majority of aquatic field microplastics (MPs) could be microfibers (MFs) which can be originated directly from massive sources such as textile production and shedding from garments, agricultural textiles and clothes washing. In addition, wear and tear of tyres (TRWPs) emerges as a stealthy major source of micro and nanoplastics, commonly under-sampled/detected in the field. In order to compile the current knowledge in regards to these two major MPs sources, concentrations of concern in aquatic environments, their distribution, bulk emission rates and water mitigation strategies were systematically reviewed. Most of the aquatic field studies presented MFs values above 50%. MPs concentrations varied from 0.3 to 8925 particles m-3 in lakes, from 0.69 to 8.7 × 106 particles m-3 in streams and rivers, from 0.16 to 192000 particles m-3 estuaries, and from 0 to 4600 particles m-3 in the ocean. Textiles at every stage of production, use and disposal are the major source of synthetic MFs to water. Laundry estimates showed an averaged release up to 279972 tons year-1 (high washing frequency) from which 123000 tons would annually flow through untreated effluents to rivers, streams, lakes or directly to the ocean. TRWPs in the aquatic environments showed concentrations up to 179 mg L-1 (SPM) in runoff river sediments and up to 480 mg g-1 in highway runoff sediments. Even though average TRWR emission is of 0.95 kg year-1 per capita (10 nm- 500 µm) there is a general scarcity of information about their aquatic environmental levels probably due to no-availability or inadequate methods of detection. The revision of strategies to mitigate the delivering of MFs and TRWP into water streams illustrated the importance of domestic laundry retention devices, Waste Water Treatment Plants (WWTP) with at least a secondary treatment and stormwater and road-runoff collectors quality improvement devices.

Continental microplastics: Presence, features, and environmental transport pathways.

Microplastics (MPs) are ubiquitous contaminants of great concern for the environment. MPs' presence and concentration in the air, soil, marine, and freshwater environments have been reported as a matter of priority in recent years. This review addresses the current knowledge of the main pathways of MPs in air, soil, and freshwater reservoirs in order to provide an integrated understanding of their behaviors in the continental environment. Therefore, MPs' occurrence (as particle counts), sources, and how their features as shape, size, polymer composition, and density could influence their transport and final sink were discussed. Wind resuspension and atmospheric fallout, groundwater migration, runoff from catchments, and water flow from rivers and effluents were pointed as the principal pathways. MPs' size, shape, polymer composition, and density interact with environmental variables as soil structure and composition, precipitation, wind, relative humidity, water temperature, and salinity. Sampling designs for MPs research should further consider soil characteristics, climate variability and extreme events, time lag and grasshopper effects, morphological and hydrological features of aquatic systems, and water currents, among others. Furthermore, long-term monitoring and lab experiments are still needed to understand MPs' behavior in the environment. This information will provide a unified understanding of the continental MPs pathways, including the key main findings, knowledge gaps, and future challenges to understand this emerging contaminant.

Assessing threats, regulations, and strategies to abate plastic pollution in LAC beaches during COVID-19 pandemic.

Plastic use and production have dramatically increased globally over the past 65 years with the improvement of life quality by the daily use of plastic products. Still, around 50% of the plastic produced is disposable products that generate substantial waste. Several reports pointed out the adverse effects of plastic litter in coastal environments in recent years, emphasizing single-use plastics (SUP). In this manner, Latin America and the Caribbean (LAC) coastal environments are highly vulnerable due to wastewater treatment facilities scarcity and poor plastic waste management strategies. Since COVID-19 pandemic, the single-use plastic waste/person rate is expected to rise due to the use of personal protective equipment and SUP as health care measures. Based on literature research and the review of plastic waste regulations, this paper will assess the main COVID-19 plastic pollution threats and LAC beaches' regulations to suggest possible measures to abate this problem. The main findings suggest that unifying the ongoing fragmented and overlapped policies is key to abate plastic pollution, including plastic industry regulations and circular economies. In addition, increasing public risk perception about plastic pollution is critical to reducing plastic waste generation. Research advances in the adverse effects of plastic debris could improve the public's perception of plastic pollution risk, pushing forward global marine plastic governance.

Valorization of Rhizoclonium sp. algae via pyrolysis and catalytic pyrolysis.

The valorization of Rhizoclonium sp. algae through pyrolysis for obtaining bio-oils is studied in this work. The reaction is carried out at 400°C, at high contact time. The bio-oil has a practical yield of 35% and is rich in phytol. Besides, it is simpler than the corresponding to lignocellulosic biomass due to the absence of phenolic compounds. This property leads to a bio-oil relatively stable to storage. In addition, heterogeneous catalysts (Al-Fe/MCM-41, SBA-15 and Cu/SBA-15), in contact with algae during pyrolysis, are analyzed. The general trend is that the catalysts decrease the concentration of fatty alcohols and other high molecular weight products, since their mild acidity sites promote degradation reactions. Thus, the amount of light products increases upon the use of the catalysts. Particularly, acetol concentration in the bio-oils obtained from the catalytic pyrolysis with SBA-15 and Cu/SBA-15 is notably high.